Product ID:BERRYMAN 2 AA C-1
MSDS Date:02/11/1988
FSC:9160
NIIN:00N050001
MSDS Number: BVJFZ

ASHLAND OIL INC

ASHLAND, KY 41101
US

Emergency Phone: 606-324-1133

Info Phone: 606-329-3333

Cage: 81355

ASHLAND INC

391 ASHLAND, KY 41114 US

Telephone: 800-622-6846

Cage: 81355

REQUIRED, THAT A SPILL HAS OCCURRED.

RTECS: 9999999ZZ

POTNTL BIRTH DEFECTS & EFTS ON REPRO SHOW

RTECS: 9999999ZZ

TO THIS MATL/ITS COMPONENTS HAS APPARENTLY BEEN

RTECS: 9999999ZZ

ABNORMS, KIDNEY/EYE/LUNG DMG, ANEMIA. OVEREXP TO

RTECS: 9999999ZZ

CARDIAC ABNORM.

RTECS: 9999999ZZ

EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT

RTECS: 9999999ZZ

CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN

RTECS: 9999999ZZ

FURTHER DMG TO THROAT. DILUTE BY GIVING

RTECS: 9999999ZZ

REMOVE INDIVIDUAL TO FRESH AIR. IF

RTECS: 9999999ZZ

GIVE ARTF RESP. KEEP PERS WARM, QUIET & GET MED

RTECS: 9999999ZZ

ADVERSELY EFFECT THE HEART W/FATAL RESULTS.

RTECS: 9999999ZZ

COMPLETED. STOP SPILL AT SOURCE, DIKE AREA OF

RTECS: 9999999ZZ

REMAINING LIQ MAY BE TAKEN UP ON SAND, CLAY, EARTH,

RTECS: 9999999ZZ

CNTNRS. PVNT RUN-OFF TO SEWERS, STREAMS/OTHER BODIES

RTECS: 9999999ZZ

LOCATION DIST FROM MATL HNDLG PT. ACID REACTS W/MOST

RTECS: 9999999ZZ

GLYCOLS POLYETHYLENE, MONO(NONYLPHENYL) ETHER; (SURFACTANT)

CAS: 9016-45-9

RTECS: MD0900000

Fraction By Weight: 1-10%

OSHA PEL N/K

ACGIH TLV: N/K

ETHYLENE OXIDE (SARA III)

CAS: 75-21-8

RTECS: KX2450000

Fraction By Weight: TRACE

OSHA PEL 1 PPM

ACGIH TLV: 1 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TALL OIL

CAS: 61790-12-3

Fraction By Weight: 1-10%

OSHA PEL N/K

ACGIH TLV: N/K

METHANE, DICHLORO-; (METHYLENE CHLORIDE)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 30-60%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE, AR-CHLORO-; (MONOCHLOROTOLUENE)

CAS: 25168-05-2

RTECS: XS8950000

Fraction By Weight: 30-60%

OSHA PEL 50 PPM, S (MFR)

ACGIH TLV: 50 PPM, S (MFR)

CRESOL; (CRESYLIC ACID) (SARA III)

CAS: 1319-77-3

RTECS: GO5950000

Fraction By Weight: 10-30%

OSHA PEL 5 PPM, S

ACGIH TLV: 5 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENE (CONTAINS ING 8)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 1-10%

OSHA PEL 100 PPM;150 STEL

ACGIH TLV: 100 PPM;150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE, ETHYL-; (ETHYL BENZENE) (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 18-20%

OSHA PEL 100 PPM;125 STEL

ACGIH TLV: 100 PPM;125 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

WHEN MATL IS TRANSFERRED. VAPS ARE HVR/AIR & MAY

RTECS: 9999999ZZ

PILOT LIGHTS, OTHER FLAMES, SPKS, HEATERS, SMOKING,

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYES:CAN CAUSE SEV IRRIT, POSS
PERM INJURY. SKIN:CAN CAUSE IRRIT. BURNS CAN RSLT FROM PRLNG CONT.
CAN BE ABSORBED IN TOX AMTS, ESP FROM PRLNG/RPTD EXPOS. INHAL:CAN
CAUSE DMG TO NASAL & RESP PASS AGES. INGEST:CAN CAUSE NAUS, VOMIT,
DIARR, IRRIT & BURNS TO STOM, MOUTH, THROAT, ETC. CHRONIC:ING 4
CAN(EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:IARC MONOGRAPHS,
SUPP, VOL 7, PG 194, 1987:GRP 2B. NTP 6TH ANNUAL RPT ON CARCINS,
1991:ANTIC (SUPDAT)
Effects of Overexposure:HLTH HAZ:RAISE LEVEL OF CARBON MONOXIDE IN
BLOOD CAUSING CVS STRESS. RSLTS OF LAB ANIMAL TESTS SHOW THAT ING 4
PRDCD:BENIGN TUMORS IN RATS EXPOS TO 500 PPM, CANCER IN RATS & MICE
EXPOS TO 1500 PPM & H IGHER. ING 4 IS NOT BELIEVED TO POSE
MEASURABLE CANCER RISK TO MAN WHEN HNDLD AS REC. LAB ANIMAL STUDIES
TO EVAL(ING 12)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN:THORO WASH EXPOS AREA W/SOAP & WATER. REMOVE & LAUNDER
CONTAM CLTHG BEFORE RE-USE. REMOVE CONTAM SHOES PROMPTLY. DISCARD
SHOES SATURATED W/THIS PROD. EYES:IMMED FLUSH W/LG AMTS OF WATER
FOR AT LS T 15 MINS, LIFTING UPPER & LOWER LIDS OCCAS. GET IMMED
MED ATTN. IF MD IS NOT IMMED AVAIL, CONTINUE FLUSHING W/WATER. DO
NOT USE CHEM ANTIDOTE. INGEST:DO NOT INDUCE VOMIT. VOMIT WILL CAUSE
(ING 18)

Flash Point Method:TCC
Flash Point:>20F,>-7C
Lower Limits:1%
Extinguishing Media:REGULAR FOAM, WATER FOG, CARBON DIOXIDE, OR DRY
CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODS MAY INCL HCL &
PHOSHENE . NEVER USE WELDING/CUTTING TORCH ON/NEAR DRUM(EVEN EMPTY)
BECAUSE PROD(EVEN JUST RESIDUE) CAN IGNITE(SUPDAT)

Spill Release Procedures:SM SPILL:ABSORB LIQ ON PAPER, VERMICULITE,
FLOOR ABSORB/OTHER ABSORB MATL. LG SPILL:ELIM ALL IGNIT
SOURCES(FLARES, FLAMES INCL PILOT LIGHTS, ELEC SPKS). PERS NOT
WEARING PROT EQUIP SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL
CLEAN-UP HAS BEEN(ING 22)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:SINCE EMPTIED CONTAINERS RETAIN
PRODUCT RESIDUES (VAPOR, LIQUID &/OR SOLID), ALL HAZ PRECAUTIONS
GIVEN IN THIS MSDS MUST BE OBSERVED.
Other Precautions:CNTNRS OF THIS MATL MAY BE HAZ WHEN EMPTIED. NO
SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL VICINITY OF ARC
WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV RADIATION MAY
CAUSE THE FORMATION O F HCL &/OR PHOSGENE .

Respiratory Protection:IF WORKPLACE EXPOS LIM(S) OF PROD/ANY COMPONENT
IS EXCEEDED, NIOSH/MSHA APPRVD AIR SUPPLIED RESP IS ADVISED IN
ABSENCE OF PROPER ENVIRON CONTROL. OSHA REGS ALSO PERMIT OTHER
NIOSH/MSHA APPRVD RESPS (N EG PRESS TYPE) UNDER SPECIFIED (SUPDAT)
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:NEOPRENE, NITRILE RUBBER/VITON GLOVES.
Eye Protection:CHEMICAL SPLASH GOGGLES & FACE SHIELD.
Other Protective Equipment:EMERGENCY EYE WASH & DELUGE SHOWER . TO
PREVENT SKIN CONTACT, WEAR IMPERVIOUS CLOTHING & BOOTS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN: TO BE CARCIN. ANIMAL:LUNG, LIVER, SALIVARY, MAMMARY
GLAND(TUMORS). RESP PROT:CNDTNS(SEE YOUR SFTY EQUIP SUPPLIER).
ENGINEERING/ADMIN CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOS. E
XPLO HAZ:EXPLO. ALL 5 GAL PAILS & LGR METAL CNTNRS INCL TANK CARS &
TANK TRUCKS SHOULD BE GROUNDED &/OR BONDED (ING 9)

Boiling Pt:B.P. Text:103F,39C
Vapor Pres:340 @ 20C
Vapor Density:HVR/AIR
Spec Gravity:GREATER/WATER
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:>95

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/STRONG OXIDIZING AGENTS, STRONG MINERAL ACIDS, STRONG
BASES, ALUMINUM.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FROM TOX MATLS, CARBON DIOXIDE &
CARBON MONOXIDE, HYDROGEN CHLORIDE, PHOSGENE, VARIOUS HYDROCARBONS,
ACID VAPS, ETC.

Waste Disposal Methods:DISPOSE OF I/A/W ALL LOCAL, STATE & FEDERAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.